Why Some Bubbles Move Faster

“We have known for about 60 years that the rise velocity of gas bubbles in viscoelastic liquids undergoes a jump at a critical bubble diameter. The speed of the bubbles can then suddenly become up to ten times faster. This plays a fundamental role in the controlled gassing of these liquids. At the same time, it was unclear what was causing this sudden increase in velocity,” explains Professor Günter Brenn from the Institute of Fluid Mechanics and Heat Transfer at TU Graz.

Polymers often consist of huge molecules that interact in complex ways with the liquid in which they are dissolved. This interaction makes a liquid viscoelastic. What causes the jump in velocity that gas bubbles display in these liquids from the critical diameter onwards?

Günter Brenn explains the latest findings: “The flow around the bubble causes the dissolved polymer molecules to stretch. The molecules do not particularly like this state. They want to return to the relaxed, unstretched state as soon as possible.” If this return to the relaxed state is faster than the transport of the molecules to the equator of the bubble, then the bubble remains slow. If, on the other hand, the return to the relaxed state takes longer than the journey to the bubble’s equator, then a tension is released in the fluid that “pushes” the bubble. This leads to a self-amplification, since subsequent polymer molecules position themselves below the equator and relax, unloading their elastic energy, releasing a “propulsive force".

In addition to the high practical relevance of this finding, especially for the above-mentioned areas of application, there are also consequences in basic research. “It turned out that another surprising property of the flow field of these solutions can be assigned to this molecular mechanism we showed: namely, the so-called ‘negative wake’ of the gas bubble,” says Dieter Bothe. This is an area in the flow field below the bubble where the fluid normally “follows” the bubble at a low velocity. With polymeric liquids, however, it is the other way round: there, the movement of the liquid is oriented in the opposite direction to the movement of the bubble. This fluid movement is caused by the same tension that “pushes” the bubble. This understanding can lead to possibilities for controlling flow processes.